State Police arrested 40-year-old Jodie Krapf of Athens over the weekend.
He's accused of molesting a teenage boy at his home over a 4-year span.
Krapf is also accused of taping a boy with a hidden video camera.
Police will not discuss the relationship between the two.
The arrest comes a week after police arrested Krapf for having 500 images of child porn on his work computer.
Krapf was the training coordinator for the Bradford Susquehanna EMS Council.
He was also a volunteer for the Greater Valley Emergency Medical Services.
Tuesday night, he's in the Bradford County Correctional Facility, awaiting his next court date.